A new environmental chamber for evaluation of gas-phase chemical mechanisms and secondary aerosol formation

A new state-of-the-art indoor environmental chamber facility for the study of atmospheric processes leading to the formation of ozone and secondary organic aerosol (SOA) has been constructed and characterized. The chamber is designed for atmospheric chemical mechanism evaluation at low reactant concentrations under well-controlled environmental conditions. It consists of two collapsible 90 m³ FEP Teflon film reactors on pressure-controlled moveable frameworks inside a temperature-controlled enclosure flushed with purified air. Solar radiation is simulated with either a 200 kW Argon arc lamp or multiple blacklamps. Results of initial characterization experiments, all carried out at 300–305 K under dry conditions, concerning NO_x and formaldehyde offgasing, radical sources, particle loss rates, and background PM formation are described. Results of initial single organic–NO_x and simplified ambient surrogate–NO_x experiments to demonstrate the utility of the facility for mechanism evaluation under low NO_x conditions are summarized and compared with the predictions of the SAPRC-99 chemical mechanism. Overall, the results of the initial characterization and evaluation indicate that this new environmental chamber can provide high quality mechanism evaluation data for experiments with NO_x levels as low as 2 ppb, though the results indicate some problems with the gas-phase mechanism that need further study. Initial evaluation experiments for SOA formation, also carried out under dry conditions, indicate that the chamber can provide high quality secondary aerosol formation data at relatively low hydrocarbon concentrations.     

The appreciation of mineral element accumulation level in some herbaceous plants species by ICP–AES method

Introduction  

From the metallurgic industry zone of Dambovita County, we harvested and analyzed seven herbaceous plants species (Lolium perenne, Festuca pratensis, Stipa capillata, Agrostis alba, Cynodon dactylon, Luzula campestris, and Agrostis tenuis) to establish the heavy metal accumulation levels in these species.     

Uptake of different forms of antimony by wheat and rye seedlings

Purpose  

The objectives of the research were to study how antimony (Sb) chemical form present in the growth medium can affect Sb uptake by plants and estimate effects of Sb on wheat and rye seedlings, in particular, assess variations in concentrations of nutrients resulting from bioaccumulation of Sb.     

A System to Monitor Climate Change with Epilithic Lichens

The issue of biological monitoring of the local consequences of anticipated global climate change is considered for the Central Negev Highlands, Israel. Epilithic lichens are suggested as biological monitors. The proposed methodology of such monitoring consists of a sampling scheme, including lichen measurement along transects on flat calcareous rocks, and construction of a trend detection index (TDI). TDI is a sum of lichen species cover with coefficients chosen so as to ensure maximum ability to detect global climate trends. Coefficients have been estimated in a study of lichens along an altitudinal gradient from 500 to 1000 m a.s.l. The gradient study demonstrated that the TDI index is performed better than other integrated indices. Recommendations on this system to monitor climate change with epilthic lichens are given. Measuring, for instance, a hundred transects in fifty plots (two transet per plot scheme) allows one to detect a climate-driven change in the epilithic lichen community corresponding to a 0.8 °C shift in annual mean temperature. Such resolution appears sufficient in view of global warming of 2.5 °C considered by the Intergovernmental Panel on Climate Change as a realistic prediction for the end of the next century.     

Alcohol, volatile fatty acid, phenol, and methane emissions from dairy cows and fresh manure

There are approximately 2.5 million dairy cows in California. Emission inventories list dairy cows and their manure as the major source of regional air pollutants, but data on their actual emissions remain sparse, particularly for smog-forming volatile organic compounds (VOCs) and greenhouse gases (GHGs). We report measurements of alcohols, volatile fatty acids, phenols, and methane (CH4) emitted from nonlactating (dry) and lactating dairy cows and their manure under controlled conditions. The experiment was conducted in an environmental chamber that simulates commercial concrete-floored freestall cow housing conditions. The fluxes of methanol, ethanol, and CH4 were measured from cows and/or their fresh manure. The average estimated methanol and ethanol emissions were 0.33 and 0.51 g cow(-1) h(-1) from dry cows and manure and 0.7 and 1.27 g cow(-1) h(-1) from lactating cows and manure, respectively. Both alcohols increased over time, coinciding with increasing accumulation of manure on the chamber floor. Volatile fatty acids and phenols were emitted at concentrations close to their detection limit. Average estimated CH4 emissions were predominantly associated with enteric fermentation from cows rather than manure and were 12.35 and 18.23 g cow(-1) h(-1) for dry and lactating cows, respectively. Lactating cows produced considerably more gaseous VOCs and GHGs emissions than dry cows (P < 0.001). Dairy cows and fresh manure have the potential to emit considerable amounts of alcohols and CH4 and research is needed to determine effective mitigation.     

Theorizing stakeholders of sustainability in the digital age

Stakeholder theory, originally introduced in 1984 by philosopher Edward Freeman, is among the most influential theories today addressing the complex interplay of societal actors. It underwent several transformations and expansions, but the original Freeman model as well as the latest approaches places the corporation at the center positioning the theory as management driven. In this article—from a sustainability science perspective—we argue that sustainability could also be considered as the center, around which societal actors are grouped, because everyone, individuals as well as stakeholders, have a stake in a ‘common future’ that is built on the transformative concept of sustainability. Next to this shift of perspective from corporation to sustainability at the center, we advance the concept of sustainability stakeholders with the new paradigm of the digital age we (are about to) live in: the proposed sustainability-centered stakeholder theory is developed to incorporate novel parameters as brought about by digitalization (such as big data, real-time transparency, algorithmic correlations, predictive analytics, or changing privacy standards). Hence, we classify the stakeholders of sustainability according to their roles as “big data stakeholders:” collectors, generators, and utilizers of big data. This digital sustainability stakeholder model operationalizes the complex interplay between stakeholders focused on their ‘stake’ in sustainability and a common future and illustrates their roles in the digital age. Thus, it offers a normative framework to analyze stakeholders’ responsibility to contribute to, advance, promote, and achieve sustainability.     

Devolving power from the state: local initiatives for nature protection and recreation in Sweden

ABSTRACT

Quests for devolving more power to local actors for nature protection stem from both international and national policies. Also, there is a growing recognition of the need for local governments to promote green infrastructure for citizens to recreate and learn about their environment. Starting in 2004, the Swedish government has allocated special funding towards these goals through the Local Nature Conservation Programme (LONA). Virtually all Swedish municipalities have received such funding in pursuit of facilitating wide access to nature and promoting recreational activities, including the protection of nature areas, creating pathways, information devices, and promoting these areas among new societal groups to enjoy. This study presents the results of ten years of experience with LONA. A survey with respondents from 191 municipalities and 20 county administrations, together with 20 key informant interviews, show that the programme has been a success in several respects. Not only have most municipalities created a wealth of new ways to engage local organisations and citizens in nature conservation and recreation, but they have also broadened the ways they think about how nature is important to their constituencies. Due to innovative ways to count voluntary work as local matching of funding, smaller and less resourceful municipalities have also become engaged. Still, the local needs for further initiatives are deemed considerable. State support coupled with knowledge sharing is important to show policy priority to such bottom-up initiatives.     

Toxicity of nanosized and bulk ZnO, CuO and TiO2 to bacteria Vibrio fischeri and crustaceans Daphnia magna and Thamnocephalus platyurus

As the production of nanoparticles of ZnO, TiO2 and CuO is increasing, their (eco)toxicity to bacteria Vibrio fischeri and crustaceans Daphnia magna and Thamnocephalus platyurus was studied with a special emphasis on product formulations (nano or bulk oxides) and solubilization of particles. Our innovative approach based on the combination of traditional ecotoxicology methods and metal-specific recombinant biosensors allowed to clearly differentiate the toxic effects of metal oxides per se and solubilized metal ions. Suspensions of nano and bulk TiO2 were not toxic even at 20 g l(-1). All Zn formulations were very toxic: L(E)C50 (mg l(-1)) for bulk ZnO, nanoZnO and ZnSO4.7H2O: 1.8, 1.9, 1.1 (V. fischeri); 8.8, 3.2, 6.1 (D. magna) and 0.24, 0.18, 0.98 (T. platyurus), respectively. The toxicity was due to solubilized Zn ions as proved with recombinant Zn-sensor bacteria. Differently from Zn compounds, Cu compounds had different toxicities: L(E)C50 (mg l(-1)) for bulk CuO, nano CuO and CuSO4: 3811, 79, 1.6 (V. fischeri), 165, 3.2, 0,17 (D. magna) and 95, 2.1, 0.11 (T. platyurus), respectively. Cu-sensor bacteria showed that toxicity to V. fischeri and T. platyurus was largely explained by soluble Cu ions. However, for Daphnia magna, nano and bulk CuO proved less bioavailable than for bacterial Cu-sensor. This is the first evaluation of ZnO, CuO and TiO2 toxicity to V. fischeri and T. platyurus. For nano ZnO and nano CuO this is also a first study for D. magna.     

Effects of sodium bisulfate on alcohol, amine, and ammonia emissions from dairy slurry

Sodium bisulfate (SBS) is extensively used in the poultry industry to reduce ammonia and bacterial levels in litter. It is also used in the dairy industry to reduce bacterial counts in bedding and ammonia emissions, preventing environmental mastitis and calf respiratory stress. The present study measured the effect of SBS on the air emission of ammonia, amine, and alcohol from a dairy slurry mix. Amine flux was undetectable (<5 ng L(-1)) across treatments. Application of SBS decreased ammonia, methanol, and ethanol emissions from fresh dairy slurry. Ammonia emissions decreased with increasing levels of SBS treatment. The 3-d average ammonia flux from the control (no SBS applied) and the three different SBS surface application levels of 0.125, 0.250, and 0.375 kg m(-2) were 513.4, 407.2, 294.8, and 204.5 mg h(-1) m(-2), respectively. The ammonia emission reduction potentials were 0, 21, 43, and 60%, respectively. Methanol and ethanol emissions decreased with an increase in the amount of SBS applied. The 3-d average methanol emissions were 223.7, 178.0, 131.6, and 87.0 mg h(-1) m(-2) for SBS surface application level of 0, 0.125, 0.250, and 0.375 kg m(-2), with corresponding reduction potentials of 0, 20, 41, and 61, respectively. Similar emission reduction potentials of 0, 18, 35, and 58% were obtained for ethanol. Sodium bisulfate was shown to be effective in the mitigation of ammonia and alcohol emissions from fresh dairy slurry.